"ELCOR" Laboratories for research in the field of
Electrochemistry and Corrosion,
University "POLITEHNICA" of Bucharest, Faculty of Industrial Chemistry
ELCOR Laboratories were founded in october 2000 in the frame of the CNCSIS
(National Council of the Universitary Scientific Research) grant financed by World
Bank, entitled: "ELCOR Programme for promoting of applied interdisciplinary
research in electrochemistry and corrosion by doctoral studies".
Location: "Polizu" site of University POLITEHNICA Bucharest, buildings E, F
and L. Mail address: Calea Grivitei 132, 78122-Bucharest, Romania.
Contact person: prof. Teodor Visan, director of ELCOR grant, tel.(+4)021 2129952
/extension 3855, 3977; (+4) 0722371083, fax: (+4)021 3154193; e-mail:
t_visan@chim.upb.ro
Laboratories and members:
- Electrochemical Studies and Corrosion Group (prof.dr.eng. Teodora Badea,
prof.dr.eng. Maria Nicola, 2 assist.prof.);
- Organic Electrochemistry Group (prof.dr.eng. Eleonora Mihaela Ungureanu,
1 eng.);
- Electrochemical Characterisation of Material in Specific Media, including
Bioliquids Group (prof.dr. Ioana Demetrescu, head of General Chemistry Dept.,
dr. Belarisa Popescu, 3 assist.prof., 1 Ph.D.student);
- Electrochemical Methods used in Electrochemistry and Corrosion Group
(prof.dr.eng. Teodor Visan, head of Appl.Phys.Chem.& Electrochem. Dept., 2
lecturers, 2 Ph.D.students);
- Electrode Processes in Electrochemistry and Corrosion with Various
Applications Group (prof.dr. Ioan Viorel Branzoi, 1 assist.prof., 2 Ph.D.students);
- "ELMIN" (Electrochemical Miniaturisation) Research Group (Dr. Danut Ionel
Vaireanu, 3 graduated students).
A series of Ph.D. students (part time), students at master program in
Electrochemistry and Corrosion (about 7-8 every academic year) and graduated
students (4-5) are involved in activities of ELCOR Lab. Until now, 12 Ph.D. students
have defended their theses under the supervisors: prof. T.Visan (11) and prof.
I.V.Branzoi (1).
Six ELCOR members are active members of Int.Soc. of Electrochemistry (ISE); there
are also members of The Electrochemical Society, USA (2), The Royal Society -
Analytical and Electrochem. Div., UK (1), European Comission of Corrosion (1),
Romanian Chem. Soc. (12) and Romanian Soc. of Chemical Engineers (8).
Photo 1. Experimental set-up for cyclic voltammetry (Sycopel potentiostat,
RDE -BAS) used by Grups 2 and 4 in the Dept. of Applied Physical Chemistry and
Electrochemistry.
Experimental facilities:
Electrochemical equipment: 3 PAR Model 173 (USA) potentiostats, a Sycopel
Scientific potentiostat (UK), all connected at PC's; RDE electrode (Bioanalytical
Syst.,USA); device for Electrochemical Impedance Spectroscopy (TFA 2000 type,
Sycopel Scientific, UK); pH-meter and conductivity-meter (Model 220, Denver
Instrument, SUA); automatic titrimeter (Metrohm E 436), Wayne-Kerr impedance bridge;
dry box (home made). Determinations: polarization curves in potentiostatic /
galvanostatic and potentiodynamic conditions, cyclic voltammetry and EIS (Nyquist
and Bode) experiments, preparative electrolyses, electrodeposition and corrosion
studies, conducting polymers, batteries, electrochemical sensors.
Research interest of Groups:
Photo 2. Electrochemical equipment containing potentiostat /galvanostat
(PAR Model 173) -used by the Group 5 in Dept. of Applied Physical Chemistry and
Electrochemistry.
- Group 1: cyclic voltammetry studies in the pollution abatement and
monitoring, polluant degrading, anodic dissolution and passivation of various
metallic materials (Ni, Cd, Zn, alloys, steel), protective organic coatings,
inhibitors;
- Group 2: kinetics and mechanisms of electrochemical processes involving
organic compounds, ions and ion radicals, organic electrosynthesis, molecular
recognition;
- Group 3: thin (passive) layers on metallic substrates, biomaterials for
implants, organic protective coatings, posibilities to perform AFM microscopy;
- Group 4: electrochemical instrumentation used in investigations of aqueous,
non-aqueous and molten salts electrolytes, mass transport studies, cyclic
voltammetry and EIS studies in electrode kinetics, electrodeposition of
semiconductor thermoelectric films, conversion coatings on Al, batteries (Pb/acid,
melts), electrochemical sensors;
- Group 5: corrosion and corrosion protection (Al in various media, steel in
petroleum industry, inhibitors), polymer electrochemistry including enzyme
entrapping, polypyrrole films.
- Group 6 (ELMIN): miniaturisation in connection with flow injection systems,
disposable sensors for biochemical applications, electrochemical minireactor for
pollution abatement and on-line electrochemical systems for pollution monitoring,
effluent contamination monitoring by virtual intruments.
Photo 3. An experimental set-up containing the potentiostat / galvanostat
(P.A.R. Model 173) connected to PC computer, used by the Group 3 in the Dept. of
General Chemistry.
Recent results and activities:
"ELCOR" Laboratories have been involved as main organizer of the 2nd International
Symposium "Electrochemistry - a Frontier Field of Theoretical and Practical Interest,
ELFI-2", held in University "Politehnica" Bucharest, September 13-15, 2001, where
the ELCOR members have presented 17 lectures, oral communications and posters
(140-total number of papers).Many scientific papers are currently published in
recognized Romanian Journals, such as: Revue Roumaine de Chimie, Roum.Chem.Quarterly
Revue, Rev.Chim., UPB Scientific Bulletin, other university and scientific journals.
More than 20 research grants and contracts (especially under the frame of national
research programmes) have contributed to the financial coverage of ELCOR research
groups, during the last two years.
Participation at the international scientific life is illustrated as following:
- - in the field of anodic oxidation of carboxylic acids and derivatives,
calixarenes, reduction processes of azomethyn compounds, molecular recognition
in solution and on modified electrodes using polypyrrole-ferrocene derivatized
films - papers published in Electrochim.Acta (1997,2001), J.Electroanalyt.Chem.,
(1996,1999), Advanced Materials (1997), Sensors & Actuators (1999), vol. "New
Directions in Org.Electrochem.", ed.A.J.Fry, Pennington, N.J.,2000, presented at
197th Meeting of Electroch.Soc, Toronto (2000), 199th
Meeting of Electrochem.Soc, Washington (2001), Int.Conf.of Chem.Societies from
South-East Europ.Countries, Halkidiki (2000), Journec d'Electrochimie, Toulouse
(1999), reported results in the frame of a francofon contract Aupelf-Uref;
- - subjects about the selection of new biomaterials according to their
electrochemical stability (aspect of biocompatibility) on the basis of the
polarization curves, open-circuit potentials and impedance spectra using electrodes
immersed in various bioliquids - presented at EMCR Conference, Budapest (May 2000),
the 51th ISE Meeting, Warsaw (2000), "Titanium in Dentistry" Symposium,
Tokyo (2001), etc.;
- - refering to the results of studies concerning: kinetics of electrode processes
with applications in corrosion, anodic dissolution and oxidation, corrosion
protection using protective phosphating layers and organic coatings,
electrodeposition of semiconductor thermoelectric compounds - can be mentioned the
papers published in journals such as: Metal Finishing-New York (1998), Materials &
Corrosion (2000), Materials Chemistry and Physics (2000), J.Solid State Electrochem.
(2001), or presented as communications at: "Surface'97", Palanga, Lituania (1997),
VI-th Corros.Symp., Izmir (1998), MSDG-RSC Annual Conf. in Chem., Edinborough (1999),
"Corros.and environmental protection", Budapest (1999), "14th Int.Corros.Congress,
Capetown (1999), Giornate dell'Electrochimica Italiana, Como (1999), ECASIA'99,
evilla (1999), EMCR, Budapest (2000), 50-th ISE Meeting, Pavia (1999), 51th ISE
Meeting, Warsaw (2000), "Eurocorr", Utrecht (1998), "Eurocorr", Heidelberg (1999), "Eurocorr", London (2000), "Eurocorr", Riva del
Garda, Italy (2001), XX Int.Conf.on Thermoelectrics, Beijing (2001).
Photo 4. Equipment for EIS experiments (Sycopel Scientific TFA 2000)
and pH-meter conductometer (Denver Instrument Model 220) - Group 4 in Dept. of
Applied Physical Chemistry and Electrochemistry
Some examples of recent papers and books:
- J.-C.Moutet, E.Saint-Aman, E.M.Ungureanu et al, Heterodinucleating macrocyclic
compounds designed for electrochemical recognition, Electrochimica Acta, 46,
2733-2740, 2001;
- N.Ibris, J.-C.Mirza-Rosca, A.Santana, T.Visan, Comparative EIS study of a
paste electrode containing zinc powder in neutral and near neutral solutions,
Journal of Solid State Electrochemistry, 6, 219-225, 2002;
- V.Branzoi, F.Branzoi, F.Golgovici, The influence of different aggressive
anions on the electrochemical behaviour of aluminium in NaNO3 aqueous
solutions, Materials and Corrosion, 51,635-641,2000;
- J.-C.Mirza Rosca, N.Ibris, M.Valles, A.Santana Lopez, T.Visan, Corrosion
atmosferica, Serv.de Reprografia y Encuadernacion, Las Palmas de Gran Canaria
University, Spain, 2000;
- I.Demetrescu, B.Popescu, General Chemistry (in romanian), Bren Publ.House,
Bucharest, 2000.
Scientific collaborations:
- national level: University of Bucharest, University "Babes-Bolyai"
of Cluj-Napoca, Univ."Ovidius" Constanta, Univ. of Oradea, Inst.Phys.Chem."I.G.
Murgulescu" of Romanian Academy, Research and Development Institute for Electrical
Engineering-Advanced Research (ICPE-CA) Bucharest, National Institute for Research
and Development for Materials Physics Magurele, Bucharest, Metallurgical Research
Institute-ICEM, Microtechnologies Institute, "Colentina" Clinic Hospital,
"Acumulatorul" Bucharest;
- international level: Univ."Las Palmas de Gran Canaria", Politecnico
di Torino, Inst.Nat.Polyt. Grenoble, Univ."Joseph Fourier" Grenoble, Aarhus Univ.,
Denmark, Sherbrooke Univ.,Canada, Hokkaido Univ., Sapporo, Marvel Thermoelectrics,
France, The Trymer Company, Leander, Texas, USA.
Photo 5. Electrochemical measurements set-up consisting in potentiostat /
galvanostat (PAR Model 173) -Group 5 in Dept. of Applied Physical Chemistry and
Electrochemistry